A Comprehensive Review of Different Synthesis Processes Involved for the Preparation of Magnesium Ferrite

DOI : 10.17577/IJERTCONV9IS11036

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A Comprehensive Review of Different Synthesis Processes Involved for the Preparation of Magnesium Ferrite

  1. Manash , S. S. Kumar, H. Satyapal, G. Kumar,

    U. Shankar

    Center for Nanoscience and Nanotechnology Aryabhatta Knowledge University

    Patna, India

    1. Das

      Department of EEE

      Birla Institute of Technology, Mesra Ranchi, India

      Abstract- An effort was made to study the different synthesis process involved in magnesium ferrite. The approaches of research of spinel ferrites show a very significant role in defining the chemical, magnetic, & structural properties. In direction to accomplish these indistinct properties, the size & morphology of MgFe2O4 have been calculated by using numerous synthetic methods i. e co precipitation, solgel, mechanochemical, combustion, microwave hydrothermal & polymerization method.

      Keywords Ferrite; Synthesis; Magnesium Ferrite; Doping


        Magnesium ferrite (Mg2+Fe3+O4) is significant magnetic oxide with cubic construction of n – spinel type. The magnesium ferrite is a magnetic quantifiable but Mg2+ ions doesnt have magnetic characteristics and the distribution phenomenon of Mg2+ ions be contingent on the synthesis temperature which directly affect some magnetic properties. The annealing progression is the important parameter which affects the magnetic possessions such as saturation & transition temperature. The growing interest in potential spinel ferrite materials with improved electromagnetic properties at higher frequencies from the magnetic, electrical, & microwave fields. The magnetic, structural, dielectrical, & electrical possessions of ferrites depend on the technique of grounding, intensity of doping, chemical configuration, annealing temperature & time [1]. MgFe2O4 is a soft ferromagnetic, n-type semiconducting material with a wide range of applications in high-density data storage devices, magnetic resonance imaging, sensors, heterogeneous catalysis, drug transport, and other fields. [2-8].

        The research of spinel ferrites participates an important part in shaping the chemical, magnetic & structural properties. The size and shape of MgFe2O4 have been studied utilizing a variety of synthetic processes, including co precipitation [9], solgel [10], mechanochemical processing

        [11], combustion method [12], microwave hydrothermal technique [13], and polymerization approach [14]. A numeral of raw ingredients can be applied in the research of ferrites; these include oxides, carbonates, oxalates, and nitrates. The previous three compounds decay to oxides on heat conduct and are therefore furnished with a temperature nearby that at which solid-state reactions originate. The homogenous material of fine quality is attained by this process. In aim of this research is to understand the different synthesis methods.

        The objective of the present study is to compare the different synthesis method used by different researcher.


Roberto Koferstein et. al [15] has taken Mg (NO3)2.6H2O & Fe (NO3)3.9H2O & transferred in 15 ml water & 2 g soluble starch were further poured & thoroughly mixed on a heating dish for 15 minutes at NTP. Afterwards temperature increases to about 120140 oC, stirred & fired until it turned into an extremely viscous red gel.

Carlos Otero Arean et. al [16] has taken MgFexGa2-xO4 and ZnFexGa2-xO4 where x is equal to 0, 0.4, 0.8, 1.2, 1.6 and 2 were ready by solid-state reaction technique in the form of polycrystalline at 947 & 1000 oC of parent oxides. MgO, Fe203, & Ga203 were taken in the first case, while ZnO, Fe203, & Ga203 were taken in the second case, and then poured in the required quantities. The nominal purity of this oxide was greater than 99.95%.

C. Doroftei et.al [17] combines sol-gel technique & self- combustion for desired samples synthesis. In comparison to traditional ceramic technology, this method yields ultra-fine, homogeneous, & repeatable ferrite dusts by using liquid solutions of metal nitrates salts. The sample configuration is Mg1xSnxFe2yMoyO4, where (x = 0 & 0.1) & (y = 0 & 0.02).

M. Bagheri et .al [18] prepared the spinel ferrite quantifiable by simply adding up the precursor nitrate mixture of magnesium & iron in C2H5OH & then dehydrated at different temperatures. The single phase MgFe2O4 was found at 900oC.

K. K. Bamzei et.al [19, 20] has taken rare earth MgDyx Fe2- xO4, where x is equal to 0, 0.01, 0.03, 0.05, and0.07 and were ready by the solid-state reaction technique. The magnesium oxide, Fe2O3 & Dy2O3 have been poured in stoichiometric proportion. The temperature maintain in the muffle furnace was 800 oC for 2h followed by annealing at 1200 oC / 2hrs with heating rate 4 oC/min.

M. J. Iqbal et.al [21] The polyethyleneglycol aided microemulsion approach produces nanosized Mg1- xCoxCrxFe2-xO4 (where x = 0 – 0.5). In well-defined quantities, liquidified solutions of correct compositions are mixed with liquid solutions of polyethyleneglycol. After the precipitates have progressed, they are heated for two hours at 300oC. The ingredients were finally annealed at 850oC for 8 hrs to attain the pure spinel segment.

S. F. Monsour et al. [22] used the co-precipitation method to generate Mn1-xMgxFe2O4 (x = 0.0, 0.1, 0.2, & 0.25) with

nano-size, in which raw materials of Fe(NO3)2.9H2O, Mn(NO3)2.4H2O, & Mg(NO3)2.6H2O were well mixed in their respective stoichiometry. Under rigorous stirring sodium hydroxide solution was dropped to become the precipitate. The pH was monitored during the adding of NaOH. The ingredient was stirred till pH shifted to 1112. The precipitate hence cleaned by using double DI water numerous times to eliminate NaCl.

R. Megha et al. [23] used an auto-combustion approach to make magnesium ferrite particles, which had previously been documented in the literature. To make a homogeneous solution, stoichiometric amounts of magnesium nitrate, ferric nitrate, & urea were put into DI water. To start the self- propagating exothermic reaction, the contents were placed in a silica crucible & heated to 300 °C using a muffle furnace until the solution ignited, releasing gaseous products and finally forming a frothy powder of ferrite nanoparticles.

C. Murugesan et. al [24] prepared Mg-Ferrite nanoparticles using solgel route. Analytical grade magnesium nitrate, citric acid & ferric nitrate as precursor. The needed amount of precursors were poured individually into 25 ml double DI water, & the resulting solutions were properly combined and magnetically agitated to achieve a homogeneous liquid. Ammonium hydroxide was used to neutralise the pH of the solution. The materials were then held at 85°C to create an extremely viscous dry gel, which was then heated on a hot plate until it self-ignited.

The pre-materials were ball-milled in the correct mole proportions, dried, & pre-sintered twice in open environment for 24 hours at 1200°C, being ground after each heating, according to R. Nathans et al. [25]. The powders were hard- pressed into discs for the final heat treatment, which included a 24 h soaking session at 1400° C, followed by a 5 h holding phase at the required temperature, & finally 5 h quenching in water.

A. A. Pandit et al. [26] used the ceramic approach to manufacture samples with the general formula Mg1+xMnxFe2- 2xO4 for 0 = x = 0.9 in 0.1-step ratios. AR grade oxides Fe2O3, MgO, & MnO2 were used as a pre-material. These oxides were thoroughly combined in stoichiomtric proportions, wet ground for four hours, & presintered for 12 hours at 900 oC.

J. Shah et al. [27,28] used a mechanical ball mill to grind analytical grade MgCO3 and Fe2O3 in a 1:1 proportion using zirconium balls. The different type of sample was obtained by mixing 0.1% and 0.3 mol% (Pr6O11) in precursor respectively which in turn was grinded for 2 h. All the 3 samples were presintered at 850ºC in open atmosphere for 8 h. These presintered powder was converted into pellet of rectangular size (15mm×3mm×2mm) which was again followed by annealing at 1000ºC in open atmosphere for 4 h.


The materials synthesis lies at the pillar of modern-day science and the growth of mankind is governed by synthesis of new advance materials. In inorganic material synthesis, high temperature combination routes are the oldest & the most practiced synthesis routes which are easily amenable to scaling up. One needs to choose proper reactants, reaction temperature, reaction duration, atmosphere, reaction crucibles. Solid state high temperature combination yields

thermodynamically stable product with preserved stoichiometry of the reactants. There a wide variation to high temperature solid state synthesis available which may reduce the reaction and duration by yielding a well homogenized reaction precursor.


The author is thankful to Aryabhatta Knowledge University, Mithapur, Patna, India for providing needful help.


  1. G. Aravind, M. Raghasudha, D. Ravinder, R.Vijaya Kumar, Magnetic and dielectric properties of Co doped nano crystalline Li ferrites by auto combustion method, J.Magn.Magn.Mater.406 (2016) 110-117.

  2. R. Sharma, P. Thakur, P. Sharma, V. Sharma, Ferrimagnetic Ni2+ doped Mg-Zn spinel ferrite nanoparticles for high density information storage, J. Alloys and Compd. 704 (2017) 717.

  3. H. Zhang, L. Li, X. Liu, J. Jiao, C.-T. Ng, J. Bao Yi, Y. Luo, B.-H. Bay, L. Zhao, M. Peng, N. Gu, and H. Fan, Ultrasmall ferrite nanoparticles synthesized via dynamic simultaneous thermal decomposition for high-performance and multifunctional T1 magnetic resonance imaging contrast agent, ASC Nano. 11 (2017) 36143631.

  4. A. Amirabadizadeh, Z. Salighe, R. Sarhaddi, Z. Lotfollahi, Synthesis of ferrofluids based on cobalt ferrite nanoparticles: influence of reaction time on structural, morphological and magnetic properties, J. Magn. Magn. Mater. 434(2017) 7885.

  5. Y. Cao, H. Qin. X. Niu, D.Jia, Simple solid-state chemical synthesis and gas-sensing properties of spinel ferrite materials with different morphologies,Ceram. Int. 42 (2016) 1069710703.

  6. A.R.O. Rodrigues, J.M.F. Ramos, I.T. Gomes, B.G. Almeida, J.P. Araujo, M.J.R.P. Queiroz, P.J.G. Coutinho, E.M.S. Castanheira, Magneto liposomes based on manganese ferrite nanoparticles as nanocarriers for antitumor drugs, RSC Adv. 6 (2016) 1730217313.

  7. Y.M. Wang, X. Cao, G.H. Liu, R.Y. Hong, Y.M. Chen, X.F. Chen,

    H.Z. Li, B. Xu, D.G. Wei, Synthesis of Fe3O4 magnetic fluid used for magnetic resonance imaging and hyperthermia, J. Magn. Magn. Mater. 323 (2011) 29532959.

  8. M. Arana, P.G. Bercoff, S.E. Jacobo, P.M. Zelis, G.A. Pasquevich,Mechanochemical synthesis of MnZn ferrite nanoparticles suitable for biocompatible ferrofluids, Ceram. Int. 42 (2016) 1545 1551

  9. Q. Chen, A.J. Rondinone, B.C. Chokumakos, Z.J. Zhang Synthesis of superparamagnetic MgFe2O4 nanoparticles by coprecipitation, J. Magn. Magn. Mater. 194 (1999) 1-7.

  10. L.J. Berchmans, R.K. Selvan, P.N.S. Kumar, C.O. Augustin, Structural and electrical properties of Ni1-xMgxFe2O4 synthesized by citrate gel process, J. Magn. Magn. Mater.279 (2004) 103-110.

  11. V. Sepelak, A. Feldhoff, P. Heitjans, F. Krumeich, D. Menzel, F.J. Litterst, I. Bergmann, K. D. Becker, Nonequilibrium cation dristibution, canted spin arrangement and enhanced magnetization in nanosized MgFe2O4 prepared by a one-step mechanochemical route,Chem. Mater. 18 (2006) 3057-3067.

  12. F. Nakagomi, S.W. Silva, V.K. Garg, A.C. Oliveira, P.C. Morais, A. Franco, Influence of the MgxFe3-xO4 nanoparticles, J. Solid State Chem. 182 (2009) 2423-2429.

  13. S. Verma, P.A. joy, Y.B. khollam, S.B. Potdar, Synthesis of nanosized MgFe2O4 powders by microwave hydrothermal method, Mater. Lett. 58 (2004) 1092-1095.

  14. H. Aono, H. Hirazawa, T. Naohara, T. Maehara, Surface study of fine MgFe2O4 ferrite powder prepared by chemical methods, Appl. Surf. Sci. 254 (2008) 2319-2324.

  15. Roberto Koferstein, Till Walther, Dietrich Hesse, Stefan G. Ebbinghaus, Preparation and characterization of nanosized magnesium ferrite powders by a starch-gel process and corresponding ceramics, J Mater Sci (2013) 48:65096518 DOI 10.1007/s10853-013-7447-x.

  16. Carlos Otero Arean, Jose L. Rodriguez Blanco and Maria C. Trobajo Fernandez, Structural Characterization of Polycrystalline Gallium- substituted Magnesium Ferrites (MgFe2Ga2-x04) and Zinc Ferrites (ZnFe2Ga2-x04), J. CHEM. SOC. FARADAY TRANS., 1992, 88(3), 321-324.

  17. C. Doroftei, E. Rezlescu, N. Rezlescu, P. D. Popa, Magnesium ferrite with Sn4+ and / or Mo6+ substitutions as sensing element for acetone and ethanol, Rom. Journ. Phys., Vol. 51, Nos. 56, P. 631640, Bucharest, 2006.

  18. M. Bagheri, M.A. Bahrevar, A. Beitollahi, Synthesis of mesoporous magnesium ferrite (MgFe2O4) using porous silica templates, Ceramics International, http://dx.doi.org/10.1016/j.ceramint.2015.05.121.

  19. K.K. Bamzai, Gurbinder Kour , Balwinder Kaur ,Manju Arora , R. P. Pant, Infrared spectroscopic and electron paramagnetic resonance studies on Dy substituted magnesium ferrite, Journal of Magnetism and MagneticMaterials345(2013)255260.

  20. K.K. Bamzai, Gurbinder Kour , B.Kaur , S.D.Kulkarni, Effect of cation distribution on structural and magnetic properties of Dy substituted magnesium ferrite, Journal of Magnetism and Magnetic Materials 327 (2013) 159166.

  21. Muhammad Javed Iqbal, Zahoor Ahmad, Turgut Meydan, Yevgen Melikhov, Temperature and composition dependence of magnetic properties of cobaltchromium co-substituted magnesium ferrite nanomaterials, Journal of Magnetism and Magnetic Materials 324 (2012) 39863990.

  22. S.F. Mansour, M.A. Elkestawy, A comparative study of electric properties of nano-structured and bulk MnMg spinel ferrite, Ceramics International 37 (2011) 11751180.

  23. R. Megha, S. Kotresh, Y. T. Ravikiran, CH. V. V. Ramana, S. C. Vijaya Kumari & S. Thomas (2016): Study of alternating current conduction mechanism in polypyrrolemagnesium ferrite hybrid nanocomposite through correlated barrier hopping model, DOI:10.1080/09276440.2016.1185298.

  24. C. Murugesan, G. Chandrasekaran, Enhanced Electrical and Magnetic Properties of Annealed Magnesium Ferrite Nanoparticles, J Supercond Nov Magn DOI 10.1007/s10948-015-3198-z.

  25. R. Nathans, S. J. Pickart, S. E. Harrison, Neutron-Diffraction studies of the Manganese-Magnesium ferrite system, Session on Molecular Interaction 621.318.132 Paper No. 2182 R Oct. 1956.

  26. A. A. Pandit, A. R. Shitre, D. R. Shengule, K. M. Jadhav, Magnetic and dielectric properties ofMg1+xMnx Fe22xO4 ferrite system, JOURNAL OF MATERIALS SCIENCE 40 (2005) 423 428.

  27. Jyoti Shah, Manju Arora, L.P. Purohit, R.K. Kotnala, Significant increase in humidity sensing characteristics of praseodymium doped magnesium ferrite, Sensors and Actuators A 167 (2011) 332337.

  28. Jyoti Shah, R.K. Kotnala, Humidity sensing exclusively by physisorption of water vapors on magnesium Ferrite, Sensors and Actuators B 171 172 (2012) 832 837.

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