- Open Access
- Total Downloads : 6
- Authors : A. Abdul Vadood
- Paper ID : IJERTCONV3IS22028
- Volume & Issue : NCEASE – 2015 (Volume 3 – Issue 22)
- Published (First Online): 24-04-2018
- ISSN (Online) : 2278-0181
- Publisher Name : IJERT
- License: This work is licensed under a Creative Commons Attribution 4.0 International License
Laser Ignition in Internal Combustion Engines a Contribution to a Sustainable Environment
A. Abdul Vadood
II YEAR MECHANICAL
Abstract – Sustainability with regard to internal combustion engines is strongly linked to the fuels burnt and the overall efficiency. Laser ignition can enhance the combustion process and minimize pollutant formation. This paper is on laser ignition of sustainable fuels for future internal combustion engines. Ignition is the process of starting radical reactions until a self- sustaining flame has developed. In technical appliances such as internal combustion engines, reliable ignition is necessary for adequate system performance. Ignition strongly affects the formation of pollutants and the extent of fuel conversion. This paper presents experimental results on laser-induced ignition for technical applications. Laser ignition tests were performed with the fuels hydrogen and biogas in a static combustion cell and with gasoline in a spray-guided internal combustion engine. A Nd:YAG laser with 6 ns pulse duration, 1064 nm wavelength and 1-50 mJ pulse energy was used to ignite the fuel/air mixtures at initial pressures of 1-3 MPa. Schlieren photography was used for optical diagnostics of flame kernel development and shock wave propagation. Compared to a conventional spark plug, a laser ignition system should be a favorable ignition source in terms of lean burn characteristics and system flexibility. Yet several problems remain unsolved, e.g. cost issues and the stability of the optical window. The literature does not reveal much information on this crucial system part. Different window configurations in engine test runs are compared and discussed.
Keywords -Laser ignition, spray-guided combustion, homogeneous combustion, high pressure, hydrogen, biogas, gasoline.
Internal combustion engines play a dominant role in transportation and energy production. Even a slight improvement will translate into considerable eductions in pollutant emissions and impact on the environment. The two major types of internal combustion engines are the Otto and the Diesel engine. The
former relies on an ignition source to start combustion, the latter works in autoignition mode. Ignition  is a complex phenomonon known to strongly affect the subsequent combustion. It
is especially the early stages that have strong implications on pollutant formation, flame propagation and quenching. The spark ignited Otto engine has a widespread use and has been subject to continuous, sophisticated improvements. The ignition source, however, changed little in the last 100 years. An electrical spark plug essentially consists of two electrodes with a gap in between where, upon application of a high voltage, an electrical breakthrough occurs.A laser based ignition source, i.e. replacing the spark plug by the focused beam of a pulsed laser, has been envisaged for some time . Also, it was tried to control autoignition by a laser light source . The time scale of a laser-induced spark is by several orders of magnitude smaller than the time scales of turbulence and chemical kinetics. In , the importance of the spark time scale on the flame kernel size and NOx production is identified. As it will be outlined in this paper, a laser ignition source has the potential of improving engine combustion with respect to conventional spark plugs.
Alternative ignition systems
The protection of the resources and the reduction of the CO2 emissions with the aim to limit the greenhouse effect require a lowering of the fuel consumption of motor vehicles. Great importance for the reduction lies upon the driving source. Equally important are the optimization of the vehicle by the means of a reduction of the running resistance as well as a low-consumption arrangement of the entire powertrain system. The most important contribution for lower fuel consumption lies in the spark ignition (SI) engine sector, due to the outstanding thermodynamic potential which the direct fuel injection provides. Wall- and air-guided combustion processes already found their way into standard-production application and serial development, whereas quite some fundamental engineering work is still needed for combustion processes of the second generation. Problems occur primarily due to
the fact that with conventional spark ignition the place of ignition cannot be specifically chosen, due to several reasons. By the means of laser induced ignition these difficulties can be reduced significantly. The combination of technologies (spray-guided combustion process and laser induced ignition) seems to become of particular interest, since the ignition in the fuel spray is direct and thus the combustion initiation is secure and non- wearing. The engine tests in this paper are on laser ignited, spray- guided combustion. Another approach is laser ignition of a homogeneous mixture. Within the scope of this paper, laser ignition in homogeneous fuel/air mixtures was investigated in a combustion bomb without turbulence. In , other alternative ignition systems than laser ignition are reviewed. Laser ignition, microwave ignition, high frequency ignition are among the concepts widely investigated. In this article the basics of applied laser ignition, will be illustrated and it potential compared to a conventional ignition system.
Laser ignition, or laser-induced ignition, is the process of starting combustion by the stimulus of a laser light source. Basically, energetic interactions of a laser with a gas may be classified into one of the
following four schemes as described in :
In the case of thermal interaction, ignition occurs without the generation of an electrical breakdown in the combustible medium. The ignition energy is absorbed by the gas mixture through vibrational or rotational modes of the molecules; therefore no well-localized ignition source exists. Instead, energy deposition occurs along the whole beam path in the gas. According to the characteristic transport times therein, it is not necessary to deposit the needed ignition energy in a very short time (pulse). So, this ignition process can also be achieved using quasi continuous wave (cw) lasers. Another type, resonant breakdown, involves non-resonant multi- photon dissociation of a molecule followed by resonant photo ionization of an atom. As well as photochemical ignition, it requires highly energetic photons (UV to deep UV region). Therefore, these two types of interaction do not appear to be relevant for this study and practical applications.
In these experiments, the laser spark was created by a non- resonant breakdown. By focusing a pulsed laser to a sufficiently small spot size, the laser beam creates a high intensity and high electric fields in the focal region. This results in a well localised plasma with temperatures in the order of 106 K and pressures in the order of 102 MPa as mentioned in [6,7].
The most dominant plasma producing process is the electron cascade process: Initial electrons
absorb photons out of the laser beam via the inverse bremsstrahlung process. If the electrons gain sufficient energy, they can ionise other gas molecules on impact, leading to an electron cascade and breakdown of the gas in the focal region. It is important to note that this processrequires initial seed electrons. These electrons are produced from impurities in the gas mixture (dust, aerosols and soot particles) which are always present. These impurities absorb the laser radiation and lead to high local temperature and in consequence to free electronsstarting the avalanche process. In contrast to multiphoton ionisation (MPI), no wavelength dependence is expected for this initiation path. It is very unlikely that the first free electrons are produced by multiphoton ionisation because the intensities in the focus (1010 W/mm2) are too low to ionise gas molecules via this process, which requires intensities of more than 1012 W/mm2 [7,9].
An overview of the processes involved in laser-induced ignition covering several orders of magnitude in time is shown in Fig. 1.
Fig 1: Scope of timescales of various processes involved in laser-induced ignition: The lengths of the double arrowed lines indicate the duration ranges of the indicated rocesses.
Laser ignition encompasses the nanosecond domain of the laser pulse itself to the duration of the entire combustion lasting several hundreds of milliseconds. The laser energy is deposited in a few nanoseconds which leads to a shock wave generation. In the first milliseconds an ignition delay can be observed which has a duration between 5 100 ms depending on the mixture. Combustion can last between 100 ms up to several seconds again depending on the gas mixture, initial pressure, pulse energy, plasma size, position of the plasma in the combustion bomb and initial temperature.
Below the main advantages of laser ignition are given: a choice of arbitrary positioning of the ignition plasma in the combustion cylinder absence of quenching effects by the spark plug electrodes ignition of leaner mixtures than with the spark plug 
=> lower combustion
temperatures => less NOx emissions [10,11]
no erosion effects as in the case of the spark plugs => lifetime of a laser ignition system expected to be significantly longer than that of a spark plug
high load/ignition pressures possible => increase in efficiency precise ignition timing possible
exact regulation of the ignition energy deposited in the ignition plasma
easier possibility of multipoint ignition [12-14]
shorter ignition delay time and shorter combustion time[10, 15-17]
fuel-lean ignition possible
The disadvantages of laser ignition are:
high system costs
concept proven, but no commercial system available yet.
This section describes the experimental setup. Laser ignition experiments were carried out in a constant volume vessel (0.9 l) and an internal combustion engine. The constant volume vessel, also termed the combustion bomb, was used to conduct basic studies of laser ignition in homogeneous fuel/air mixtures. The sustainable fuels hydrogen and biogas were used. The biogas was obtained from a municipal water purification plant. It was composed of 50.5% CH4, 31.7% CO2 and 80 ppm H2S. Schlieren photography was used for accompanying optical diagnostics.
The engine, a one-cylinder research engine, was deployed for the investigation of sprayguided combustion initiated by a laser. Gasoline was used as a fuel here. The focus of sustainability is on laser ignition for enhanced combustion and efficiency.
Laser ignition and concurrent Schlieren photography in a combustion bomb
The laser ignition experiments in the constant volume vessel were carried out with hydrogen and biogas. The xperimental setup and tests with methane are outlined in .
A pulsed Nd:YAG laser with pulse energies from 1 to 50 mJ was used for the ignition tests.
Table 1 lists the specifications of the laser. Schlieren photography was conducted in the plane of the focal spot of the igniting laser.
Perpendicularly to the igniting laser beam, a collimated light beam from a flash lamp (1 s pulse duration) was shone through the combustion vessel. As the diffraction index of light depends on the type and mass density of a gas, areas with different temperatures or different pressures have different diffraction indices. So a parallel beam of light is diffracted at differences of temperature and pressure and the diffraction angle is proportional to the first derivate of these parameters . The experimental setup for the Schlieren experiments is outlined in .
Laser ignition in an internal combustion engine
A one-cylinder research engine was used as a test engine. The research engine was equipped with a four-valve DOHC cylinder head with a spray-guided combustion system of AVL List GmbH . In a double-overhead-camshaft (DOHC) layout, one camshaft actuates the intake valves, and one camshaft operates the exhaust valves. Gasoline was used as a fuel. The same laser as in the combustion bomb tests in 2.1 was used (see Table 1).
NCEASE-2015 Conference Proceedings
Table 1: Technical data of the laser. A solid-state laser was used here.
In Table 2 the key technical data of the test engine are listed.
Table 2: Technical key data of the test engine. A spray- guided research engine running on gasoline was used.
Engine test runs were carried out with two different approaches.
First, a plane window was inserted into the cylinder head of the engine. A focusing lens was
placed in front of that window in order to focus the laser beam down into the combustion
bomb (separated optics).
Second, a more sophisticated window was deployed. A lens- like curvature was engraved
directly into the window. By using such a special window, no further lens was required
This is depicted schematically in Fig. 2.
Fig. 2: Schematic cross section of the engine for laser ignition test runs. Two window/lens configurations were tested:
Fig. 2(a) shows the separated optics, Fig. 2(b) the combined optics.
RESULTS AND DISCUSSION
3.1.1. Laser ignition of hydrogen/air mixtures
Fig. 3 depicts a pressure history of combustions for different mixtures () at an initial chamber temperature of 473 K and an initial pressure of 1 MPa. Comparable pressure histories could be seen for higher initial pressures. is the so called air/fuel equivalence ratio: < 1 signifies a fuel-rich mixture, whereas
> 1 describes a fuel-lean mixture.
Between = 2.5 and 3.6 (14.4% and 10.4% H2) an oscillating pressure history could be
observed having a frequency in the lower kHz region which is the resonant frequency of the combustion bomb . The oscillating combustion process is called knocking, which meansthat the combustion propagates not only by a spherical flame front, starting from the plasma but also that the mixture explodes at different locations in the end-gas (unburned gas) as an effect of self ignition conditions . With rich hydrogen- air mixtures ( < 3.6) the flame propagates at a specific instant during the combustion time with sonic velocity through the gas and produces high pressure and temperature values in the end-gas region leading to auto ignition . This auto ignition process produces shock waves which are reflected from the chamber walls and end in oscillations which can be observed in Fig. 3 for a between 2 and
3.6. Knocking is very disadvantageous for engine applications.
Fig. 3: Pressure history in the combustion bomb after ignition applying minimum pulse energy for ignition (MPE); = 1.8 – 5; initial temperature = 473 K, initial pressure = 1 MPa; If the air/fuel equivalence ratio () is increasing (leaner mixtures), the peak pressure is decreasing but the total combustion time is increasing.
Pressure histories for a constant gas mixture ( = 3.5) and constant initial temperature (T = 473 K) but different initial filling pressures are plotted in Fig. 4. The main result of this diagram is that with higher initial pressures the minimum pulse energy for ignition (MPE) is decreasing like it was observed for methan-air mixtures in [2,6,9,10]. Further on, it can be seen that with higher initial pressures, which means higher energy contents in the combustion bomb , the peak pressures increases. Gas mixtures with = 3.5 represent the leaner boundary where knocking starts, as depicted in Fig. 4.
Fig. 4: Pressure history in the combustion bomb after ignition applying minimum pulse energy for ignition (MPE); = 3.5, initial temperature = 473 K, initial pressure = 1 4.2 MPa; For higher initial pressures the peak pressure, ignition delay and total combustion time is increasing but the minimum pulse energy for ignition (MPE) is decreasing.
Especially at this boundary knocking occurred only at lower filling pressures. With higher initial filling pressures no knocking could be observed. Richer gas mixtures only have a knocking combustion with no dependency on the filling pressure.
Laser ignition of biogas/air mixtures
Biogas is CO2-neutral and can act as a promising alternative fuel having a high availability. The two most common sources of biogas are digester gas and landfill gas. Bacteria form biogas during anaerobic fermentation of organic matters. The degradation is a very complex process and requires certain environmental conditions. Biogas is primarily composed of CH4 (50-70%) and CO2 (25-50%). Digester gas is produced at sewage plants during treatment of
municipal and industrial sewage. Landfill gas is obtained during decomposition of organic waste in sanitary landfills. When using biogas as fuel one must also pay attention to several harmful ingredients such as H2S polluting e.g. the catalytic converter of the engine or blocking the window of the laser (see later for issues related to the window). With respect to laser ignition, biogas was compared to methane. The investigated methane/air and biogas/air mixtures contained similar methane concentrations but in the case of biogas additionally CO2 was present. Fuel-lean biogas/air mixtures exhibit a slower combustion process resulting in lower peak pressure and flame emission compared to methane-air mixtures of similar air to fuel equivalence ratio. The reason for these results could be due to the presence of CO2 in the biogas which reduces the burning velocity due to obstructing the flame propagation during combustion. SO2 may also be responsible for the decreased burning rate of the biogas/air mixtures reducing mainly the O-radical concentration to equilibrium state due to the recombination of the O-radicals. In Fig. 5, images of the developing flame kernel in laser ignited biogas/air mixtures are depicted (see below).
Fig. 5: Schlieren photographs of laser ignition, laser entering from the left side. The images are 11.6 mm long and 9.15 mm high.Top row: Laser-induced spark and shock wave in 25 bar air; From left to right: 500 ns, 1000 ns, 2000 ns, 3000 ns. Middle row: Laser-ignition of H2/air mixtures at 25 bar, lambda 6.0; From left to right: 100 s, 200 s, 300 s, 1000 s. Bottom row: Laser-ignition of biogas/air mixtures at 25 bar, lambda 1.8; From left to right: 100 s, 900 s, 1800 s, 15000 s.
More details on laser ignition of biogas/air mixtures can be found in .
Shockwave and flame kernel development by Schlieren photography
Schlieren photography was used to obtain visual information on the shock wave formation and flame kernel development. Schlieren photography is an experimentally uncomplicated technique that has been applied successfully to the investigation of laser ignition, too. However, the literature contains very scarce information on pressures higher than ambient. In this study, high pressure tests were done. Fig. 5 shows Schlieren photographs of laser ignition test runs. In all images, the laser enters from the left side. The images are 11.6 mm long and 9.15 mm high. In the top row, images of the laser-induced spark and shock wave in pure air at 25 bar can be seen.
In the middle row, consecutives images of laser-ignition of H2/air mixtures at 25 bar and lambda 6.0 are shown.
The bottom row shows Schlieren images of laser-ignition of biogas/air mixtures at 25 bar and lambda 1.8. The shock wave carries two major implications on laser ignition: First, it transports energy away from the ignition spot. Second, it causes a significant temperature rise. When the shock wave has detached from the hot core air, both phenomena can be studied independently. The shock wave initially has an ellipsoidal shape caused by the asymmetric energy deposition of the laser.
Results and trends from the literature, predominantly existing in the ambient pressure regime, could be verified using Schlieren photography. More information on Schlieren photography of laser ignition can be found in .
Engine tests were conducted to investigate the optical window with respect to
Durability of the optics (vibrations)
Minimum ignition energy
Wear and fouling properties of the inner window surface The engine tests were conducted with gasoline. Whereas the focus of the previous tests and ongoing work in a static combustion bomb was on the understanding of the ignition process, the aim of the engine tests was to investigate the durability of the optical window.
Optics deposits and self-cleaning effect
As stated above, laser ignition is based on the principle of optical breakdown and thus it is essential to provide the necessary intensity which is approximately 1011 W/cm2 in the focus.
The energy emitted from the laser is attenuated by reflections on the surface of the window and the lens and by absorption in the lens, in the combustion-chamber window and in the deposits on the windows. The transmission of typical windows in the infrared is
approximately 90%; the reflections on the surfaces further reduce the energy. Adding it up,
when the laser beam passes through a window or a lens, the losses amount to approximately 15%. The laser self-cleaning effect was studied with deposits from the true combustion process (3.2.2), and also with artificially applied deposits (3.2.3).
Laser self-cleaning with deposits caused by the combustion process
Fig. 6 shows the cold start performance of the engine with a soiled window. Here, the deposits
stemmed from a real combustion process inside the engine (see  for details).
Fig. 6: Cold start performance with soiled combustion bomb window deposits because of engine-related combustion process
These deposits, which were caused by the combustion process, were built up during the tests with a conventional spark plug. Thereby the combustion- chamber window was installed in different load points, the engine running mode being homogeneous, for about 20 hours. As it can be seen in Fig. 6, the window was soiled with a dark and opaque layer of
combustion deposits after these 20 hours.
In the simulated cold-start test with a stratified engine running mode with 1000 rpm (rotations per minute) and pMEP = 1 bar, the pMEP course was recorded for each cycle, as shown in Fig. 6 (MEP = mean effective pressure). The first ignition and injection impulse occurred at cycle 10. The first laser impulse already ignites the mixture. The following ignition impulses resulted in a running without misfire. After the test (100 cycles) the window was disassembled and, as visible in Fig. 6, all deposits were removed in the beam passage area.
Laser self-cleaning with worst case deposits
In order to study the effect of the laser on a heavily soiled window, it was chosen to artificially apply a layer of dirt onto the window. This artificially applied soiling on the combustion-chamber side of the window represents a kind of worst case scenario.
For doing so, a mixture of Diesel soot and waste oil at a ratio of 1:5 was produced and, with a thickness of 1 mm, applied to the combustion-chamber window and afterwards dried.
Fig. 7 shows the clea influence of the laser energy on the self-cleaning effect of the optics.
Fig. 7: Misfire rate dependent on the relative laser energy in a simulated cold start test, comparison of the optics, worst case deposits
Up to a build-up energy of the threshold energy ES, an engine operation without misfire is possible with a separated optics configuration, presupposed that a corresponding pulse number for the burning-off of the window is shot. This build- up energy ES is significantly higher in combined optics when aiming to reach a misfire rate of 0%. The relative laser energy was replaced by the actually occurring relative energy intensity I on the combustionchamber side of the window in Fig. 8.
Fig. 8: Influence of the energy intensity I at the combustion bomb window on the burn off performance and the misfire rate, worst case deposits
An engine operation without misfire with both optics configurations, i.e. separated and combined optics (see Fig. 2), is possible as of a build-up intensity of IS. In separated opticsthis build-up intensity IS corresponds to the build-up energy of ES.However, the minimum intensity for keeping the combustions-chamber window clean duringthe engine running is IS/2.The minimum ignition energy when the engine running is stationary is determined by theintensity level of self-cleaning at the optics, and not by the engine- related working process. Inthe whole engine operating map a secure ignition and self- cleaning of the optics can beguaranteed with the laser energy ES.For cold start applications, the laser energy should thus be raised momentarily in order to burnoff possible deposits at the optics.
Fig. 9: Laser energy for ignition as a function of different window configurations. The separated optics, i.e. a focusing lens before a window, is less favorable than a combined optics, i.e. a window with integrated lens curvature, with respect to the minimum ignition energy.
Fig. 9 shows the laser energy for the different window configurations (compare Fig. 2). Both the minimum ignition energy (left bar) and the laser energy for a 20 hour test run (right bar) are shown.
As it can be clearly seen, the combined optics are more favorable than the separated optics with respect to required laser energy.The energy density at the window is a major criterion for the ablation of combustion bomb deposits.
During cold start, heating up and in the case of existing deposits only a high laser energy density can ensure the ablation effect at the location of the laser. The energy density is therefore an important determinant on the reliability of a future laser ignition system.
self- cleaning effect as shown above is achieved by the laser. Sapphire, quartz and ZnSe are among potential window materials in a future laser ignited engine.  reviews the major infrared transparent substrates suitable for window fabrication.
Fig. 10: Energy density at the window. It is higher for the separated optics. The higher the energy density, the better ablation works. The separated optics scheme should therefore be more reliable than the combined optics.
As it can be seen from Fig. 10, the energy density is by an order of magnitude higher for the separated optics than for the combined optics for the chosen configuration. The separated optics scheme leads to a higher energy density at the window. Especially in the case of cold start or unexpected deposits, this setup should be more reliable than the combined optics.
As can be seen from Fig.9 and Fig. 10, there is a trade-off between low laser energy requirements (combined optics) and system reliability (separated optics).
From an engine manufacturers point of view, system reliability comes first, which translates into higher required laser energies and hence higher system costs.
Properties of the optical window
Potential window materials evidently have to be transparent for the laser radiation. The laser used in these tests was a Nd:YAG laser at 1064 nm. The near infrared spectral region is a common wavelength region for laser suitable for laser ignition test runs. So infrared transparent windows are good candidates for a future laser ignition system. The second, no less important prerequisite is that the window withstand the high energy density of the laser. The shorter the focal length of the lens, the higher generally the laser light intensity of the passing laser beam becomes at the window surface. Third, the window must show a weak inclination to deposits and aid laser self- cleaning. Combustion bomb deposits can either be organic (up to 300Â°C) or inorganic in nature. When they form on the window, they increasingly block the incoming laser light up to a point where no breakdown can be produced any more. In , for instance, laser ignition tests of methane/air mixtures in an engine had to be aborted after
1.25 hours because of excessive combustion product build-up. ZnSe was used in that study. The formation of deposits on the window depends on the temperature, the fuel and the engine oil.The laser light also interacts with deposits. By a process called laser cleaning or ablation , deposits are removed by the laser light. The contrary can also happen, i.e. that the laser fosters the formation of deposits at the location where it enters the combustion chamber. Generally, ablation overweighs so that a kind of
In this work, laser-induced ignition of hydrogen/air and biogas/air mixtures was investigated experimentally in a static combustion bomb. An enhanced ignition source can make a strong contribution to sustainability in internal combustion engines. Schlieren photography was applied to gain information on the shock wave propagation and early flame kernel development.
Results and trends from the literature, predominantly existing in the ambient pressure regime, could be verified. It was found for the laser ignition tests with hydrogen that with higher initial pressures the minimum pulse energy for ignition (MPE) decreases. That behaviour was also found for methane.
Fuel-lean biogas/air mixtures exhibit a slower combustion process resulting in lower peak pressure and flame emission compared to methane-air mixtures of similar air to fuel equivalence ratio. The applicability of the laser induced ignition as a future ignition system for combustion engines with spray-guided combustion process could be proved with the basic research. The lowest required ignition energy in a stationary engine running mode is defined by the intensity level of the self- cleaning effect at the optics and not by the engine-related working cycle. In order to prevent deposits on the optics by the combustion process, a certain build-up intensity IS has to be available on the combustion bomb side of the window in order to ensure an engine operation without misfire. The energy intensity necessary to keep the burnt off optics clean during the normal engine operation is, however, lower. Half the build-up intensity IS has proven to be sufficient in order to prevent deposits. From the point of view of components development, the main goal is the creation of a laser system which meets the engine- specific requirements. Basically, it is possible to ignite mixtures with different laser systems. The concept with the greatest development potential regarding efficiency and miniaturization is the diode pumped solid-state laser.
This work was supported by the Austrian Industrial Research Promotion Fund (FFF) under Grant FFF 803050 and by the A3 project number 806238/7782.
The authors want to thank Heinrich Kofler for his contribution with work related to the optical window. They also want to thank Kurt Iskra for his contribution to the Schlieren photography.
Lackner, M., Winter, F., What is ignition? Combustion File 256, IFRF Online Combustion Handbook, ISSN 1607-9116, International Flame Research Foundation, Ijmuien, The Netherlands, (2004).
H. Kopecek, M. Lackner, F. Winter, E. Wintner, Laser ignition of methane air mixtures at pressures up to 4 MPa, Journal of Laser Physics 13 (11), 1365 (2003).
Kopecek, H., Lackner, M., Wintner, E., Winter, F., Laser- Stimulated Ignition in a Homogeneous Charge Compression Ignition Engine, SAE 2004 World Congress, paper No 2004-01-0937, Detroit, MI, USA (2004).
J. D. Dale, M. D. Checkel, P. R. Smy, Application of High
Energy Ignition Systems to Engines, Prog. Energy Combust. Sci. 23, 379-398 (1997).  Ronney P.D., Laser versus conventional ignition of flames, Optical Engineering 33(2), 510 (1994).
Phuoc T.X., White F.P., Laser-induced spark ignition of CH4/air mixtures, Combustion and Flame 119, 203-216 (1999).
Radziemski L.J., Cremers D.A., Laser-induced plasmas and applications, New York- Basel: Marcel Dekker Inc., (1989).
Yablonovich E., Self phase modulation and short pulse generation from laser breakdown plasmas, Phys. Rev. A10, 1888-1895 (1975).
Phuoc T., Laser spark ignition: experimental
determination of laser-induced breakdown thresholds of combustion gases, Optics Communication 175, 419-423
Kopecek H., Charareh S., Lackner M., Forsich C., Winter F., Klausner J., Herdin G., Wintner E., Laser Ignition of Methane-Air Mixtures at High Pressures and Diagnostics, Salzburg, Austria: Proceedings of ICES03, Spring Technical Conference of ASME Internal Combustion Engine Division (2003).
Heywood J.B., Internal combustion engine fundamentals, McGraw-Hill international editions (1988).
Phuoc T.X., Single-point versus multi-point laser ignition: Experimental measurements of combustion times and pressures, Combustion and Flame 122, 508- 510 (2000).
Morsy M.H., Ko Y.S., Chung S.H., Cho P., Laser- induced two point ignition of premixture with a single- shot laser, Combustion and Flame 125, 724-727 (2001).
Morsy M.H., Chung S.H., Laser induced multi-point
ignition with a single-shot laser using two conical cavities for hydrogen/air mixtures, Experimental Thermal and Fluid Science 27, 491-497 (2003).
Weinrotter M., Kopecek H., Wintner E., Lackner M., Winter F., Laser ignition of hydrogen-air mixtures at high pressures, Orleans, France: Proceedings of the European Combustion Meeting, European Combustion Institute (2003).
Ma J.X., Alexander D.R., Poulain D.E., Laser spark ignition and combustion characteristics of methane-air mixtures, Combustion and Flame 112, 492-506 (1998).
Ma J.X., Ryan III T.W., Buckingham J.P., Nd:YAG Laser ignition of natural gas, ASME Spring Technical Conference, Paper No. 98-ICE-114 (1998).
Gary S. Settles, Schlieren and shadowgraph techniques, Springer (2001).
M. Lackner, S. Charareh, F. Winter, K. F. Iskra, D. RÃ¼disser, T. Neger, H. Kopecek, E. Wintner, Diagnostic tools for laser-induced ignition of gaseous mixtures: Schlieren photography and laser-induced fluorescence spectroscopy (LIF), to be submitted to Optics Express (2004).
Josef Graf, Untersuchungen zur laserinduzierten
ZÃ¼ndung an einem Otto-DI Brennverfahren der zweiten Generation (Investigation of laser-induced ignition of an Otto direct injection engine of the 2nd generation), Master Thesis, Vienna University of Technology, Vienna, Austria (2002).
Christian Forsich, Maximilian Lackner, Franz Winter, Herbert Kopecek, Ernst Wintner, Characterization of Laser-Induced Ignition of Biogas/air Mixtures, accepted for publication, Biomass & Bioenergy (2004).
Bernhard Geringer, Dominikus Klawatsch, Josef Graf, Peter Lenz, Dieter SchuÃ¶cker, Gerhard Liedl, Walter F. Piock, Markus Jetzinger, Paul Kapus, Laserzuendung, MTZ 65(3), 214-219 (2004).
Boris Lukyanchuk, Laser Cleaning, Optical Physics, Applied Physics and Materials Science, World Scientific Publishing, Singapore (2002).  Daniel C. Harris, Durable 3-5 m transmitting infrared window materials, Infrared Physics and Technology 39, 185-201 (