Characterization of Materials by X-Ray Diffraction

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Characterization of Materials by X-Ray Diffraction

Dr. A. K. Ghatage, Prof. S. G. Kanitkar

D K T E Societys Textile and Engineering Institute, Ichalkaranji

Abstract:- X rays are electromagnetic radiation of wavelength about 1 Ao, which is about same sise of an atom. X- ray diffraction provides information that cannot be obtained any other way. This information relates to the crystal lattice of the material and can characterize the crystalline phases present. This paper provides the background of the use and theory of x-ray powder diffraction. Here polycrystalline ferrite with the chemical composition Ni0.5 xZn0.5TixEe2 2xO4 system with x = 0.0, 0.1, 0.2, 0.3, 0.4 and 0.5 were prepared by ceramic and characterized by x-ray diffraction.

INTRODUCTION:

X rays are electromagnetic radiation of wavelength about 1 Ao, which is about same sise of an atom. They occur in that

portion of the electromagnetic spectrum between gamma rays and ultra violet radiations. Thediscovery of x-rays enabled scientists to probe crystalline structure of the atomic level. X-ray diffraction has been in use , for the finger print characterization of crystalline materials and in determination of their structures. Each crystalline solid has its unique characterics x-ray powder pattern which may be used as a fingureprint for its identification. Once the material has been identified, x-ray crystallography may be used to determine its structure. X-ray diffraction is one of the most important characteristics tools used in solid state physics, chemistry and materials science.

Braggs Equation of X ray Diffraction:

Figure1

Diffraction of an x ray beam striking a crystal occurs because the wavelength of x ray beam is similar to the spacing of atoms ( 1AU). When an x-ray beam encounters the regular three dimensional arrangement of atoms in a crystal. Most of x-rays will destructively interfere with eachother, but in some specific directions they constructively interfere and reinforce the another.

W L Bragg showed that diffracted x-rays act as if they were reflected from a family of planes within crystals. Bragg;s planes are the rows of atoms that make up the crystal

structure. These reflections were shown to only occur under certain conditions which satisfy the equation

2dSin = n

Where n= is an integer

= wavelength of x rays

d = distance between atomic planes

= the angle of incidence of x-rays beam and atomic planes for a given wavelength of incident x-rays and interplanar spacing in a material, only specific angles will satisfy the Braggs equation

INSTRUMENTATION:

Figure2

The x-ray diffraction experiment requires an x-ray source, the sample under investigation and a detector to pick up the diffracted x-rays.

The schematic diagram of powder x-ray diffractometer is as shown in figure. The x-ray radiation most commonly used is that emitted by copper, whose characteristic wavelength of the k radiation is 1.514 AU. When the incident beam strikes a powder sample, diffraction occurs in every possible orientation of 2 . The diffracted beam may be detected by using a movable detector. In normal use, the counter is set to scan over a range of 2 at a constant angular velocity. Routinely the angular range of 5 degree to 79 degree is sufficient to cover the most useful part of the powder pattern. The scanning speed of the counter is usually of 2 degree per minute

APPLICATIONS:

x-ray diffraction has wide range of applications in geology, material science, environmental science, chemistry, forensic science and the pharmaceutical industry among others. Researchers use x-ray diffraction to characterize materials from a wide veriety of settings. Some examples are

  1. Many plastic polymers have sme order and can be identified and studied by x-ray diffraction methods

  2. Many structures such as polymers, drawn fibers, rolled and forged metals or thin films deposited by various methods show varying degree of anisotrophy. This information relating to preferred crystalline orientation textures can be quantified and evaluated by x ray diffraction methods.

  3. In studies of areas affected by acid mine drainage, the identification of secondary materials and fine grained precipitates is a critical element

  4. Minerals form under specific ranges of pressure and temperature. Mineralogical identification of ore minerals and associated minerals including fine grained hydrothermal alteration minerals provides evidence

    used to deduce the condition under which ore deposites formed and the conditions under which in many cases they were subsequently altered

  5. X-ray diffraction is one of the primary tools used to evaluate the lateral and vertical variation in mineral matter amd majoe, minor and trace elements in coal beds

ANALYSIS OF X-RAY DIFFRACTION:

In the days of digital x-ray diffraction patterns, Rietveld Analysis(Rietveld 1969) has played a very important role. This a whole pattern treatment rather than a limited number of reflections of the x-ray data and it gives the type of structural analysis. Normally obtained by a single crystal diffractometer. It is originally conceived as a refinement method for crystal structures using neutron diffraction data. But today it is also used for x-ray diffraction. Briefly, the Reitveld method requires a knowledge of the approximate crystal structure of all phases of interest. The input data obtained to calculate a synthetic pattern includes the space group symmetry, number of atoms. Atomic positions, temperature factor, site occupancies and lattice parameters. The refinement is conducted by minimizing the sum of the weighted, squared differences of this calculated pattern and the observed intensities every step in a digital powder pattern. In a typical refinement, individual scale factors ( related to the weight percent of each phase) and profile, background and lattice parameters are varied. Since the method uses all lines, severally overlapping reflections are not a problem. The method can obtain the following crystallographic information.

Lattice parameters: since systemetic errors ( caused by sample displacement) are corrected during refinement, accurate values up to one part in 1000 can be obtained on solid samples without an internal standard. Additionally accurate cell dimensions can be computed on low symmetry materials.

Accurate Phase quantification: scale factors are refined and are related to weight percent of each phase. Complex mixtures with overlapping reflections are quantified with high degree of accuracy ( about 1 %)

Crystallite size and strain: A mathematical function is used to model the profiles and to separatr diffraction peak broadening due to size from that due to strain. Size and microstrain values are derived simultaneously from x-ray diffraction pattern.

Site Occupancies: This yields quantitative information as to the extent of solid solution or isomorphous substitution.

Atom positions: positions of selected cations in the unit cell can be computed.

X-ray Diffraction of Fewrrite System: X-ray diffraction study is carried out for ferrites Ni0.5 xZn0.5TixEe2 2xO4 with x = 0.0, 0.1, 0.2, 0.3, 0.4 and 0.5 were obtained at inter University Consortium Indore. All the samples are prepared by ceramic method and all the samples were in the form of powder and copper k radiations were used. The diffraction patterns were taken with the angle range btween 10 degree to 70 degree.

Table 1: Observed and calculated values for Ni0.5 Zn0.5Ee2 O

hkl

220

311

222

400

422

333/511

440

d- observed

2.9737

2.5337

2.4183

2.0924

1.7138

1.6164

1.4838

D calculated

2.9695

2.5323

2.4224

2.0997

1.7144

1.6163

1.4847

Table 2: Physical constants of Ni0.5 xZn0.5TixEe2 2xO4

Composition

Moleculat wt Gm-mol

Measured density gm/cc

x-ray density gm/cc

Porosity

%

Lattice parameter a

Ao

Ni0.5 Zn0.5Ee2 O4

237.73

4.24

5.342

20.6

8.390

Ni0.56Zn0.5Ti0.1Ee1.8O4

237.22

4.21

5.331

21.03

8.392

Ni0.7xZn0.5Ti0.2Ee1.6O4

236.71

4.16

5.305

21.58

8.399

Ni0.8Zn0.5Ti0.3Ee1.4O4

236.21

4.16

5.332

21.83

8.395

Ni0.9Zn0.5Ti0.4Ee1.2O4

235.69

4.05

5.283

23.33

8.399

Ni01.0Zn0.5Ti0.5Ee1.0O4

235.19

4.04

5.277

23.44

8.396

Figure3: X ray diffraction pattern for Ni0.5 Zn0.5Ee2 O4

For the case of Ni0.5 xZn0.5TixEe2 2xO4 system. From the study it is seen that, for all the samples, the lattice constant remained constant. Here in this case the two ions of Fe2+ are substituted by Ni2+ and Ti4+ions. The ionic radii of all these

ions are nearly same (0.67 AU)/ \\. Therefore the constancy in lattice constant may be because of constant ionic radii.

The x-ray density, actual density and porosity of samples have been determined and presented in table.

Figure4. Profile fitted pattern with magnetic reflections for Ni0.5 Zn0.5Ee2 O4

CONCLUSION:

/It is seen from above discussion that x-ray diffraction is a powerful tool for characterization of materials and much useful information can be obtained frpm it.

Acknowledgement:

Authors are thankful to management and Director of Textile and Engineering Institute, Ichalkaranji for their encouragement.

REFERENCES:

  1. Ph. D. Thesis Neutron diffraction studies on Tetravalent substituted Mg-Zn and Ni-Zn ferrites by Dr A K Ghatage(1996)

  2. Beagg W L Nature(London) 95(1955) 361

  3. USGS information handout may 1997

  4. GEOS 443mineralogy by Prof. Goring Oct.1998

  5. Klug H P and Alexander L L: X ray diffraction procedures for polycrystalline and amoephous materials, second edition, John Wiley New York and London 1974

  6. Neutron Diffraction Study of Ti substituted Ni Zn Ferrites. Indian Journal of Physics A(1999) 329-335

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